Effect of strain rate on primary water stress corrosion. All holders of operating licenses or construction permits for pressurized. Two regions are possible, one at the start potential for passive films or the pit nucleation potential and a second at. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Sep 10, 20 a pwscc mechanism based on an ordering reaction in alloy 600 is proposed. Different npp components are subjected to different damage mechanisms depending on the type of material used, the way it is manufactured, and the exposure environments. Effects of dissolved hydrogen on the primary water stress. Primary water stress corrosion cracking pwscc of inconel 600. Primary water stress corrosion cracking in pwrs history of pwscc in pwrs, control rod drive mechanism and bottom mounted instrument nozzle pwscc, pwscc mechanism. Recently, a number of cracks due to primary water stress corrosion cracking pwscc have been detected in nickelbased alloy welds in the primary piping of pressurized water reactors pwrs.
Corrosionpedia what is stress corrosion cracking scc. Primary water stress corrosion cracking nuclear power suggest new definition. The ordering reaction in alloy 600 causes an anisotropic. A pwscc mechanism based on an ordering reaction in alloy 600 is proposed. Primary water stress corrosion cracking pwscc mechanism based on ordering reaction in alloy 600. It is the gradual destruction of materials usually a metal by chemical andor electrochemical reaction with their environment. Evaluation of primary water stress corrosion cracking growth rates. This report summarizes the status of our current understanding on mechanisms of stress corrosion crack initiation and propagation in alloy 600 pwr steam generator tubes. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment.
If you have insulated solid stainless steel equipment operating in the cui temperature range you are likely to eventually experience external chloride stress corrosion cracking ecscc. Weld residual stresses and primary water stress corrosion. An overview is given of current understanding of mechanisms of stress corrosion cracking in metals. Pdf for alloy 600, primary water stress corrosion cracking pwscc is one of the key material degradation mechanisms in pressurized water. Pits can act as stressconcentration sites which can be initiation points for stressrelated corrosion mechanisms. Primary water stress corrosion cracking of highchromium, nickelbase welds near dissimilar metal weld interfaces nuregcr7226 on this page. Primary water stress corrosion cracking pwscc is one key form of degradation in extended service scenarios. Pdf evaluation of primary water stress corrosion cracking. Corrosion is a natural process that converts a refined metal into a more chemicallystable form such as oxide, hydroxide, or sulfide.
This type of failure is known as stress corrosion cracking, often abbreviated to scc. For alloy 600, primary water stress corrosion cracking pwscc is one of the key material degradation mechanisms in pressurized water reactors pwrs. The stress corrosion cracking scc of aluminum alloys is a welldocumented phenomenon, but there is considerable disagreement in the scientific literature as to what mechanism causes it. Primary water stress corrosion cracking pwscc of inconel 600 addressees. Stress corrosion may result in either intercrystalline or transgranular cracking of carbon steel. Stress corrosion cracking archives engineered thermal.
Stress corrosion cracking of stainless steels and nickel. For alloy 600, primary water stress corrosion cracking pwscc is one of the key material degradation mechanisms in pressurized. Improvement of probabilistic fracture mechanics analysis code. It can occur during operation as a result of inleakage of air at pumps, or failure in operation of preboiler water treatment equipment. Flowchart of the usersubroutine for the primary water stress corrosion cracking assessment. Evaluation of primary water stress corrosion cracking growth. Stresscorrosion cracking experiments can be categorized as. Corrosion and its mitigation in light water reactors lwrs. Primary water stress corrosion cracking pwscc of inconel 600 united states nuclear regulatory commission office of nuclear reactor regulation washington, d. It also excludes intercrystalline or transcrystalline corrosion, which can disintegrate an alloy without applied or residual stress. Stress corrosion cracking the international institute of.
Understanding the mechanisms controlling low potential. In addition to the large diameter hot leg pipe, cracking in other piping components of different sizes has been. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Primary water stress corrosion cracking pwscc mechanism. Stress corrosion cracking mechanisms of alloy 600 polycrystals and single crystals in primary waterinfluence of hydrogen. Primary water stress corrosion cracking how is primary. Stress corrosion cracking mechanisms of alloy 600 polycrystals and. Nuclear reactors nickel alloys primary water stress corrosion cracking. Effect of water chemistry on igscc, crack growth rate modeling and mitigation of igscc in bwr stainless steel piping.
Keywords stress corrosion cracking, alloy 600, alloy 690, primary water, scc, crack initiation, sims, tem, intergranular corrosion. Destructive testing has been conducted on damaged heaters to determine the origin of cracking. It is pointed out that most materials are potentially susceptible to stress corrosion cracking. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Primary water stress corrosion cracking pwscc of alloy 600 has been a great concern to the nuclear power industry. The aim of the present paper is to analyze the predominant mechanisms of iascc of austenitic steels in the lwr primary coolant environment and to develop a model for. Intergranular stress corrosion crack initiation and temperature dependence of alloy 600 in pressurized water reactor primary water presented in the corrosion in nuclear systems symposium as part of the corrosion 2018 conference. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Grain boundary selective oxidation and intergranular. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Stresscorrosion cracking scc is a cracking process that requires the simultaneous action of a corrodent and sustained tensile stress. Stress corrosion cracking of alloy 600 in pwr primary. One of the main failure mechanisms that cause risks to pressurized water reactors pwr is the primary water stress corrosion cracking pwscc occurring in alloys like the alloy 600 75ni15cr9fe. Mechanisms and modeling of stress corrosion cracking in.
Therefore, the structural integrity assessment for primary piping taking pwscc into consideration has become important. Stress corrosion cracking of nickel based alloys in water. Tensile weld residual stresses, in addition to service loads, contribute to pwscc primary water stress corrosion cracking crack growth. It is caused by the joint effect of tensile stress, temperature, susceptible metallurgical microstructure and environmental conditions of the primary water. Grain boundary selective oxidation and intergranular stress. Stress corrosion cracking international institute of. Various corrosion mechanisms contribute to boiler tube failure. Analysis of mechanisms inducing corrosion cracking of.
Stress corrosion cracking results from the conjoint action of three components. Amp 103 water chemistry version 2017 programme description the main objective of this programme is to mitigate loss of material due to corrosion, including flowaccelerated corrosion fac, cracking due to stress corrosion cracking scc and related degradation mechanisms, and reduction of heat transfer due to fouling in components exposed to a treated water environment. The obtained results show that, even if the dissolutionoxidation seems to be the first and necessary step. The primary water stress corrosion cracking pwscc of alloy 600 uns n06600, type 304 uns s30400, and type 316 uns s31600 stainless steels ss was studied at 360c and at nominal strain rates ranging from 1. Iaea nuclear energy series technical reports stress corrosion cracking in light water reactors. Also, there are clear similarities in the primary water stress corrosion cracking pwscc phenomena between ass and nickel base alloys such as alloy 600. Mechanisms of stresscorrosion cracking 3 the characteristics of each of these stages are subsequently discussed in greater detail.
Primary water stress corrosion cracking pwscc in bimetal. Critical analysis of alloy 600 stress corrosion cracking. This alloy is wellknown to be susceptible to stress corrosion cracking scc in pwr primary water. Corrosion engineering is the field dedicated to controlling and preventing corrosion in the most common use of the word, this means. Primary backup link criticalitybased routing algorithm. Primary water stress corrosion cracking pwscc testing of an alloy 600182 weld was conducted at 325 c for 20,725 h in a simulated primary water environment of a pressurized water reactor. Stress corrosion cracking scc studies in stainless steels and nickel alloys reveal that all grades and conditions are susceptible to scc in hightemperature water, whether deaerated or aerated, high h 2 or low, theoretical purity water or bufferedcontaminated, lower temperature or higher. Stress corrosion crack initiation of alloy 600 in pwr primary water. Stress corrosion cracking in light water reactors iaea scientific. Saji searched for possible mechanisms that may have been overlooked, judged insignificant or. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. It is the stresses level that exceeds the yield point 16. Our approach involves isolating the effects of single variables in scc crack initiation or propagation, which has been instrumental in revealing the effect of coldwork, water temperature, alloy composition and stress level on scc and the controlling mechanisms under lowpotential conditions pwr and abwr 5.
Therefore, irradiation assisted stress corrosion cracking iascc can be considered as one of the mechanisms potentially limiting the lifetime of rpv internals components. Stress corrosion cracking of alloy 600 in pwr primary water. Primary water stress corrosion cracking of highchromium. Light water reactor sustainability program materials aging.
In the area of welding technology, two critical longstanding welding. One of the main failure mechanisms that cause risks to pressurized water reactors is the primary water stress corrosion cracking occurring at the control reactor displacement mechanism nozzles. Fac, corrosion fatigue cf, and irradiationassisted stress corrosion cracking iascc can act in combination with each other to magnify their individual effect. Reliable pwscc growth rate data, especially at temperatures in the range of 290330c, of the alloy are required in order to evaluate the lifetime of power plant components. Primary water stress corrosion cracking how is primary water stress corrosion cracking abbreviated. Pdf primary water stress corrosion cracking pwscc mechanism. Indications of stress corrosion cracking resistance in alloy 82 dissimilar metal welds in simulated primary water environments suraj persaud master of applied science chemical engineering and applied chemistry university of toronto 2011 abstract joints between carbon steel and alloy 600, containing alloy 82 weld metal, were exposed to. Mechanical factors in primary water stress corrosion.
Pdf a pwscc mechanism based on an ordering reaction in alloy 600 is proposed. In this study, three tests were carried out in simulated pressurized water reactor pwr primary water. Chapter 14 boiler system failures suez water technologies. Purchase stress corrosion cracking of nickel based alloys in water cooled nuclear reactors, volume 67 1st edition. Generic letter 9701, degradation of control rod drive mechanism nozzle and. Identification of the mechanism responsible for primary water stress corrosion cracking pwscc in nickelbase alloys is a controversial topic. Primary water stress corrosion cracking pwscc is an intergranular cracking mechanism in which cracks form in susceptible materials under.
The most severe stress corrosion problem to affect pwrs is igscc of alloy 600 in pwr primary water sometimes called pwscc for pressurized water stress. Regions where stress corrosion cracks are viable can be related to the potentiodynamic scans for passive materials. Oxygen pitting occurs with the presence of excessive oxygen in boiler water. Good practices and lessons learned international atomic energy agency vienna isbn 978920. The obtained results show that, even if the dissolutionoxidation seems to be the first and necessary. For example, in the pw conditions, both types of materials show lower susceptibility to the igscc in sensitized conditions tice et al. This mechanism can be proved by the comparison of the initiation behavior in the ordered and the disordered specimens. Two alloy 600 control rod drive mechanism crdm heats and one plate heat were. Despite the fact that many laboratory studies have been performed and that many models are proposed in the literature, the mechanisms involved are still not wellknown. However, the mechanism for pwscc in inconel 600 is still not well understood.
Oxygen has been detected in themetal grain boundaries under the oxide scale. It is caused by a combination of metal stress and the presence of a corrosive. Irradiation assisted stress corrosion cracking iascc the cracking of materials exposed to ionizing irradation is associated w austenitic stainless steel materials in high temperature water under neutronirradiation exposure, which alters material properties and produces radiolsis of water. The cracking, mainly confined to the inconel weld metal, is caused by corrosion mechanisms. Current nrc perspectives concerning primary water stress. However, the kinetics of scc growth vary enormously with stress intensity, yield strength. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. It was revealed that the pwscc fracture mode of these materials changed with. This excludes corrosionreduced sections that fail by fast fracture. Primary water stress corrosion cracking pwscc is an intergranular cracking mechanism in which cracks form in susceptible materials under corrosive. Mechanical factors in primary water stress corrosion cracking. Microstructural comparison of intergranular attack in alloy 600 in the sa versus tt. Aggressive localized boiler tube corrosion and loss of tube wall.
Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. The former is a vector used to define the indices for all the failure mechanisms, and the latter is an array used to define the normal to the fracture plane in 3d or the line in 2d, for each failure mechanism. Examinations are evaluating grain boundary corrosionoxidation mechanisms and the influence of carbides on degradation. Nuregcr5752, anl994, assessment of current understanding. The primary systems corrosion research program improves the useful life of primary system components in boiling water and pressurized water reactors through a deeper understanding of the crack initiation and early propagation processes involved in stress corrosion cracking and irradiationassisted stress corrosion cracking. Major contributors to primary water stress corrosion cracking in pressurized. Alloy 600, a nickel base alloy containing 15 % chromium, is used in the primary circuit of pressurized water reactor pwr. Chloride cracking of austenitic stainless steels 300 series ss is an offshoot of cui, and theres nothing really magical about it. Implication of such a finding on the crack initiation mechanisms in alloy 600 is discussed. In order to study the mechanisms involved in the stresscorrosion cracking scc of alloy 600 in primary water, the influence of the relevance of physicochemical and metallurgical parameters was assessed. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Pits can act as stress concentration sites which can be initiation points for stress related corrosion mechanisms causes. In order to study the mechanisms involved in the stress corrosion cracking scc of alloy 600 in primary water, the influence of the relevance of physicochemical and metallurgical parameters was assessed.
Factors influencing stress corrosion cracking and various mechanistic and empirical. The coriou effect presents the latest information on brittle failure of metals in corrosive chemical environments under the influence of tensile stresses nickel alloys are more resistant to scc as well as high temperatures and have been widely used in more challenging environments such as nuclear power plants. Stress corrosion cracking of nickel based alloys in watercooled nuclear reactors. Primary water stress corrosion cracking behavior of an. Understanding the mechanisms controlling low potential stress. Prediction of pure water stress corrosion cracking pwscc. An activation energy for the ordering reaction in alloy 600, q. Evaluation of primary water stress corrosion cracking. It can occur, besides another places, at the control rod drive mechanism crdm nozzles.
One of the main failure mechanisms that cause risks to pressurized water reactors pwr is the primary water stress corrosion cracking pwscc occurring in. Prediction of pure water stress corrosion cracking pwscc in. Aug 20, 2009 the cracking, mainly confined to the inconel weld metal, is caused by corrosion mechanisms. Sep 25, 2015 destructive testing has been conducted on damaged heaters to determine the origin of cracking. Indications of stress corrosion cracking resistance in. Primary water stress corrosion cracking pwscc became a concern for nickelbased components in pwrs in recent years. Early during the life of pwrs, scc of steam generator tubes was an important issue. Primary water stress corrosion cracking pwscc mechanism based on ordering reaction in alloy 600 springerlink. Numerous mechanisms, including the filmruptureoxidation i. The ordering reaction in alloy 600 is an indispensable process during reactor operating conditions. Intergranular cracking occurred only in the regions of alloy 182 weld metal, which suggests that alloy 182 weld metal is more susceptible to pwscc than. The postulated mechanisms for stress corrosion cracking of. It can occur during operation as a result of inleakage of air at pumps, or failure in operation of preboiler water. Primary water stress corrosion cracking listed as pwscc.
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